Iridium-Catalyzed Enantioselective Hydrogenation of Olefins.
β Scribed by Andreas Pfaltz; Joerg Blankenstein; Robert Hilgraf; Esther Hoermann; Steven McIntyre; Frederik Menges; Marc Schoenleber; Sebastian P. Smidt; Bettina Wuestenberg; Nicole Zimmermann
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 53 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Cationic iridium complexes with chiral phosphinooxazoline ligands are efficient catalysts for the enantioselective hydrogenation of olefins. The complexes are readily prepared, air-stable, and easy to handle. In contrast to chiral rhodium- and ruthenium-phosphine catalysts, they do not require the p