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Iridium-Catalyzed Enantioselective Hydrogenation of Olefins

✍ Scribed by Andreas Pfaltz; Jörg Blankenstein; Robert Hilgraf; Esther Hörmann; Steven McIntyre; Frederik Menges; Marc Schönleber; Sebastian P. Smidt; Bettina Wüstenberg; Nicole Zimmermann

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
245 KB
Volume
345
Category
Article
ISSN
1615-4150

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Enantioselective hydrogenation of olefin
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Cationic iridium complexes with chiral phosphinooxazoline ligands are efficient catalysts for the enantioselective hydrogenation of olefins. The complexes are readily prepared, air-stable, and easy to handle. In contrast to chiral rhodium- and ruthenium-phosphine catalysts, they do not require the p