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IR-spectroscopy study of the conformational equilibrium of morpholine molecules

โœ Scribed by B. N. Narziev; M. Nurulloev


Publisher
SP MAIK Nauka/Interperiodica
Year
1987
Tongue
English
Weight
361 KB
Volume
27
Category
Article
ISSN
0022-4766

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NMR data, in CCl 4 , show that an increase in the concentration of cis-3-ethoxycyclohexanol (cis-3-ECH) shifts the conformational equilibrium from the ax-ax conformer (X ax-ax Z51% at 0.01 mol L K1 ), stabilized by an intramolecular hydrogen bond (IAHB), to the eq-eq conformer (X eq-eq Z67% at 0.40