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Study of the conformational equilibrium of trans-1-alkoxymethyl-2-halogenocyclohexanes by means of ir and PMR spectroscopy

โœ Scribed by U. Kh. Agaev; A. Z. Shikhmamedbekova; S. Z. Rizaeva; A. T. Alyev

Publisher
SP MAIK Nauka/Interperiodica
Year
1980
Tongue
English
Weight
324 KB
Volume
20
Category
Article
ISSN
0022-4766

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Concentration and solvent effects on the
Concentration and solvent effects on the conformational equilibrium of cis-3-ethoxycyclohexanol by 1H NMR and IR spectroscopy
โœ Paulo R. de Oliveira; Danilo S. Ortiz; Roberto Rittner ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 149 KB

NMR data, in CCl 4 , show that an increase in the concentration of cis-3-ethoxycyclohexanol (cis-3-ECH) shifts the conformational equilibrium from the ax-ax conformer (X ax-ax Z51% at 0.01 mol L K1 ), stabilized by an intramolecular hydrogen bond (IAHB), to the eq-eq conformer (X eq-eq Z67% at 0.40