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IR Matrix Isolation and ab Initio Identification of Products of the Reactions of CH 3 Cl and CH 3 Br with Mg

✍ Scribed by Solov'ev, Viktor N.; Sergeev, Gleb B.; Nemukhin, Alexandr V.; Burt, Stanley K.; Topol, Igor A.

Book ID: 126398318
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 306 KB
Volume: 101
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp971968t

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## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m