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IR and visible luminescence studies in the infrared multiphoton dissociation of 1,2-dibromo-1,1-difluoroethane

✍ Scribed by K.K. Pushpa; Awadhesh Kumar; R.K. Vatsa; P.D. Naik; K. Annaji Rao; J.P. Mittal; V. Parthasarathy; S.K. Sarkar

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
556 KB
Volume
240
Category
Article
ISSN
0009-2614

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✦ Synopsis

The infrared multiphoton dissociation of 1,2-dibromo-l,l-difluoroethane gives rise to IR and visible luminescence. Vibrationally excited parent molecules dissociate via two primary channels yielding bromine and vibrationally excited HBr.

The strong visible emission observed between 350 to 750 nm has been assigned to electronically excited carbene CF,BrcH.

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