✦ LIBER ✦
Anomalous gas pressure effects in infrared multiphoton dissociation of molecules of the homologous series CnH2n + 1OH (n = 1–4)
✍ Scribed by Victor N. Bagratashvili; Mikhail V. Kuzmin; Rustem R. Osmanov; Felix N. Putilin; Ludmila N. Vereshchagina
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 444 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Thr producrion of OH radicals in inrrxrd mulripholon dissociaIion or C,,H2,,+, OH (II = l-4) bomolo~~ has hccn sludied. -Ihe OH yield has been round LO drop abnormally rapidly with increasing gas pressure of alcohols with II > 2. Possible rsxson.s for Ihe obsen-cd e.fCecl. such M redislribulion or intramolecular vihraGonal energy within ~hc &xxronic ground sl;lls and :I non-adiabatic vibr;llional-elrclronic wmsiIion. are discussed.