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IPSO-substitutions. Reactions of 3-substituted indoles with benzoylperoxide

✍ Scribed by Martino Colonna; Lucedio Greci; Marino Poloni

No coin nor oath required. For personal study only.

✦ Synopsis

3-substituted indoles with benzoylperoxide led to the 3-benzoyloxy derivative.The on is discussed in terms of homolytic ipso-substitution.

Recently we observed that nitronium and nitrosonium ions1 reacted with 3-substituted indoles reactito form 3-nitroindole.

In this letter we report the results for tine reaction between 3-substituted indoles and benzoylperoxide.

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