Ionization energies of CH3O• and CH3S• radicals measured by charge-inversion energy-loss spectrometry
✍ Scribed by W.J. Griffiths; F.M. Harris
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 234 KB
- Volume
- 142
- Category
- Article
- ISSN
- 0009-2614
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Double-ionization energies of CH 3 Br, CH 2 Br 2 and CHBr 3 to singlet and triplet electronic states of their dications were calculated and measured. Double-charge-transfer spectroscopy was employed in the experimental part of the study; the computational work was carried out using a semi-empirical
A kinetic study has been made of the gas phase, I,-catalyzed decomposition of (CH&S at 630-650 K. Some I, is consumed initially, reaching a steady-state concentration. The initial major products are CH4 and CH,S together with small amounts of CH3SCHZI, CHSI, HI, and CS2. The initial reaction corresp