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Ionization constants and structure of seven- and eight-membered cyclic phosphorous acid derivatives

✍ Scribed by V. V. Ovchinnikov; O. A. Cherkasova; É. G. Yarkova; N. A. Mukmeneva; A. N. Pudovik; R. A. Cherkasov

Book ID
112438742
Publisher
Springer
Year
1978
Tongue
English
Weight
235 KB
Volume
27
Category
Article
ISSN
1573-9171

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✍ Frank A.L. Anet; Ragini Anet; Michael P. Trova; Leo A. Paquette 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 301 KB

The conformations and conformational dynamics of the two title hydrocarbons have been determined by lH 500 MHz NMR and molecular mechanics calculations; barriers for the Cope rearrangements are also reported. The semibullvalene (SBV) molecule (1) has a rigid tricyclic stmcture (C, point group symme