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Ionization and dissociation equilibriums in liquid sulfur dioxide. 12. The behavior of tetrahedral ions

✍ Scribed by Lichtin, Norman N.; Wasserman, Bernard; Clougherty, Edward; Wasserman, June; Reardon, John F.


Book ID
120535208
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
935 KB
Volume
84
Category
Article
ISSN
0022-3654

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On the Electrochemical Oxidation of CsβŠ•
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The electrochemical oxidation of the alkali‐metal ions Cs^βŠ•^, Rb^βŠ•^, K^βŠ•^, and Na^βŠ•^ appears to occur in liquid sulfur dioxide, but only at about + 4.7 V vs. SCE, as shown by studies on their AsF and PF salts for which other sources of the observed oxidation waves could be excluded. No evidence for