## Abstract The ionisation energies and the HeI photoelectron spectra of the Nβoxides of diazabenzenes are presented. The valence electronic structures of the Nβoxides are discussed in view of the ionisation energies, and the profiles, of the bands. The interpreted data are compared to calculations
Ionisation energies and electronic structures of the phenyl 1,3-dipoles
β Scribed by J. Bastide; J.P. Maier; T. Kubota
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 765 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0368-2048
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Spin-coupled theory is applied to the four xelectrons of the 1,3-dipoles nitrone and diazomethane. The orbitals for both molecules take the form of distorted out-of-plane 2p functions, but one of the orbitals in nitrone is delocalized over two centres. The description is dominated by one mode of cou
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