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Ionisation Energies and the Electronic Structures of the N-oxides of Azanaphthalenes and azaanthracenes

✍ Scribed by John P. Maier; Jean-François Muller; Tanekazu Kubota; Masumi Yamakawa


Publisher
John Wiley and Sons
Year
1975
Tongue
German
Weight
822 KB
Volume
58
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The HeI photoelectron spectra of the N‐oxides of the azanaphthalenes 15 and of the azaanthracenes 6, 7 were ascertained. The inferred ionisation energies, and the assignments of the spectra, are presented and are discussed in respect to the electronic structures of the N‐oxides and the spectra of the azaderivatives. The data supports the description of the electronic structures of the basic heterocyclic N‐oxides based on PPP SCF calculations and the electronic abrosption spectroscopy.


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