## Abstract The ionisation energies and the HeI photoelectron spectra of the N‐oxides of diazabenzenes are presented. The valence electronic structures of the N‐oxides are discussed in view of the ionisation energies, and the profiles, of the bands. The interpreted data are compared to calculations
Ionisation Energies and the Electronic Structures of the N-oxides of Azanaphthalenes and azaanthracenes
✍ Scribed by John P. Maier; Jean-François Muller; Tanekazu Kubota; Masumi Yamakawa
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- German
- Weight
- 822 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The HeI photoelectron spectra of the N‐oxides of the azanaphthalenes 1–5 and of the azaanthracenes 6, 7 were ascertained. The inferred ionisation energies, and the assignments of the spectra, are presented and are discussed in respect to the electronic structures of the N‐oxides and the spectra of the azaderivatives. The data supports the description of the electronic structures of the basic heterocyclic N‐oxides based on PPP SCF calculations and the electronic abrosption spectroscopy.
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