Ionisation and dissociation of hexafluoroethane, and of 1,1,1-trifluoroethane and fluoroform, by electron impact
β Scribed by K.A.G. MacNeil; J.C.J. Thynne
- Publisher
- Elsevier Science
- Year
- 1969
- Weight
- 828 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0020-7381
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The thermal, unimolecular elimination of HF from CH3CF3 was studied by three different groups over the temperature range 1000" to 1800Β°K. While the reported kinetic parameters varied greatly, it is shown here that these data may be satisfactorily correlated in terms of a four-center transition state
## Abstract Disagreements in rate constants and parameters between published results on the decomposition of 1,1βdifluoroethane and 1,1,1βtrifluoroethane are shown to originate from incorrect specification and setting of reaction conditions in one of the studies. When corrected, applicable results