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Ionic Lewis superacids in the gas phase. Part 3. Reactions of gaseous CF+3 with nitrogen bases

✍ Scribed by Felice Grandinetti; Giorgio Occhiucci; Maria Elisa Crestoni; Simonetta Fornarini; Maurizio Speranza

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 778 KB
Volume: 127
Category: Article
ISSN: 0168-1176
DOI: 10.1016/0168-1176(93)87086-8

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CF3 radicals were generated by the photolysis of perfluoroacetic anhydride. In the presence of pentafluorobenzene, the CF3 radicals react according to the following mechanism: It was found that the addition reaction (3) becomes reversible above ca. 453 K. The addition rate parameters have been rev