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Ion-solvent interaction: Viscosity and apparent molar volume of univalent electrolytes in dioxane-water mixtures at different temperatures

✍ Scribed by N.C. Das; P.B. Das

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
321 KB
Volume
25
Category
Article
ISSN
0013-4686

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✦ Synopsis

The viscosity and apparent molar volume ofNaC1, NaBr, NaNO,, KCI, KBr and KNO,, at mass fractions of dioxane of lo,20 and 309/ have been studied at 30,35,40 and 45°C. The values of the A and E coefficients of the viscosity equation indicate ion-ion and ion-solvent interactions. The limiting apparent molar volume (V) and limiting slope (S,) is found to be different for different salts at different solvent compositions and has also been interpreted in terms of ion-ion and ion-solvent interaction.

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📜 SIMILAR VOLUMES

Viscosity, apparent molar volume and con
Viscosity, apparent molar volume and conductivity of chlorides, bromides, nitrates, bromates, iodates and sulphates of potassium and sodium in dioxane+water mixtures at 35°C
✍ P.B. Das 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 250 KB

The viscosity, apparent molar volume and conductivity of the chlorides, bromides, nitrates, bromatcs, iodatcs and sulphatcs of potassium and sodium at mass fraction of dioxane (IO, 20 and 30 'x) + water mixtures at 35'C f 0.01 have been measured. The ions appear to interact and the ion-solvent inter