Ion-solvent interaction of uniunivalent electrolytes in dioxane-water mixtures from conductivity data
✍ Scribed by N.C. Das; P.B. Das
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 243 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
✦ Synopsis
Abstmc'
The ion-solvent interaction of N&I, KCI, NaBr, KBr, NaNO, and KNO, at mass fraction of dioxane (10, 20 and 3Oc)%kwater mixtures at 30, 35, 40 and 45°C & 0.01 has been studied using electrolytic conductivity data and Walden product. The ions appear to interact appreciably and the ion-solvent interaction is of the order NO; > Br-> c1-.
📜 SIMILAR VOLUMES
The viscosity and apparent molar volume ofNaC1, NaBr, NaNO,, KCI, KBr and KNO,, at mass fractions of dioxane of lo,20 and 309/ have been studied at 30,35,40 and 45°C. The values of the A and E coefficients of the viscosity equation indicate ion-ion and ion-solvent interactions. The limiting apparent
Conductance measurements are reported for several salts in binary aqueous mixtures containing up to 60 mole y0 sulfolane, 20 mole % acetonitrile and 20 mole % dimathylsulfoxida. The variations of R = (A$~o),/(A~qo), with solvent composition have been compared with those observed in other water-rich