𝔖 Bobbio Scriptorium
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Ion Solvation in Water–Acetonitrile Mixtures

✍ Scribed by R. D. Mountain

Book ID
110239964
Publisher
Springer
Year
2001
Tongue
English
Weight
125 KB
Volume
22
Category
Article
ISSN
0195-928X

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📜 SIMILAR VOLUMES

Variation of fluoride ion solvation and
Variation of fluoride ion solvation and pF− buffer properties of HF2−/HF and HF/H+ pairs in acetonitrile-water mixtures
✍ J. Bessiere; F. Bazine 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 510 KB

The F-ion is weakly solvated in acetonitrile-water mixtures. In the mixture with 50% (mole) of water, the fluoride ion solvation transfer activity coefficient is logi = 5.1; it increases up to 16.7 in anhydrous acetonitrile. In these two mixtures, the equimolar buffer HF/H+ imposes pF-values of 6.4