Ion-pair formation in the photodissociation of HF and DF
✍ Scribed by Yencha, Andrew J.; Hopkirk, Andrew; Grover, J. Robb; Cheng, Bing-Ming; Lefebvre-Brion, Hélène; Keller, Françoise
- Book ID
- 120561502
- Publisher
- American Institute of Physics
- Year
- 1995
- Tongue
- English
- Weight
- 433 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.470501
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## Abstract Excitation functions for both positive and negative ions (X^+^ + Y^−^), formed by photodissociation in the vicinity of the onset of molecular ionization, for the jet‐cooled interhalogen systems BrCl, ICl and IBr are reported. The overall shape of the excitation functions indicates that
Pbotodissociative production of ion pairs from Hz has been observed in the wavelength range 706-718 A at spectral resoWions of 0.4 and 0.22 A. From measured thresholds for production of H-from Hz molecules in each of the three lowest rotational states, the lower bound EAf.H) 5 0.754 \* 0.002 eV is o