Ion-ion hybrid resonances of H2- and D2-discharges
✍ Scribed by H. Schlüter; G. Schürger
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 155 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0375-9601
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We report the 488 nm photoelectron spectra of the mass-selected Cr2H-and Cr& anions. The electron affinity of Cr2H is 1.474 k 0.005 eV. Frequencies are reported for all three vibrational modes in both the neutral molecules and the anions, and their structures and bonding properties are discussed.
Using a sudden transition state theory we find that photodissociation of long-lived resonances of DzH+ leads to the H+ fragment for total angular momentum JC 27 while D+ is formed for J> 30. This quantum result which is critically dependent on the difference of zero-point energies between D2 and HD