Weak acid ion-exchange membranes were obtained on the basis of PVC/poly(MMA-co-DVB) interpolymer-type systems. Carboxylic groups were introduced by acid hydrolysis of ester groups in poly(MMA-co-DVB) copolymer. It was found that suitable conditions for preparation of carboxylic membranes were: tempe
Ion-exchange membrane based on poly(styrene sulfonic acid-co-n-(2-hydroxyethyl) acrylamide)
✍ Scribed by Tetsuya Tanigami; Hiroshi Iwata; Takamasa Mori
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 389 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
A new ion‐exchange membrane was prepared by blending a copolymer of poly(styrene sulfonic acid‐co‐N‐(2‐hydroxyethyl) acrylamide) with poly(vinylidene fluoride). The dissolution of the copolymer into water was prevented by the crosslinked network formed by condensation reaction between N‐(2‐hydoroxyethyl) acrylamide (HEAA) units. The reaction was caused after film‐forming the blend. Swellability in water, ion‐exchange capacity, ion conductivity, and mechanical properties of the membrane were investigated and compared with those of a well‐known ion‐exchange membrane, Nafion 117. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2788–2796, 2007
📜 SIMILAR VOLUMES
The transport of nickel and copper through a carboxylic ion-exchange membrane was investigated by using a system containing HC1 as a receiver solution and nickel chloride or copper chloride as a feed solution. The transfer rate was found to be greatly affected by the H+ concentration in the receiver