𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Ion cyclotron resonance studies of ambident nucleophiles. The reactions of the trimethylsilyl cation with alkenyl ethers and alkoxy ketones

✍ Scribed by Marie F. Dottore; V. Craige Trenerry; David J. M. Stone; John H. Bowie


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
431 KB
Volume
16
Category
Article
ISSN
1076-5174

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Ion cyclotron resonance studies of alkyl
✍ Ian A. Blair; V. Craige Trenerry; John H. Bowie 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB

## Abstract Diallyldimethylsilane provides a source of the allyldimethylsilyl cation in the ion cyclotron resonance spectrometer; reaction of this cation with alcohols (ROH) produces adducts which decompose by loss of C~3~H~6~ to yield the ion \documentclass{article}\pagestyle{empty}\begin{document

Electron impact studies: CXXXI—Ion cyclo
✍ V. Craige Trenerry; John H. Bowie 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB

## Abstract The [MeCOS]^−^ ion undergoes reaction with neutral thioacetic anhydride in an ion cyclotron resonance cell to yield an adduct [M+MeCOS]^−^ which decomposes principally by loss of CH~2~CS, thus establishing the occurrence of nucleophilic attack through O at the carbonyl centre.