✦ LIBER ✦
Electron impact studies: CXXXI—Ion cyclotron resonance studies of ambident nucleophiles. The reaction between the thioacetate anion and thioacetic anhydride. A further example of a negative ion McLafferty rearrangement
✍ Scribed by V. Craige Trenerry; John H. Bowie
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 183 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
Abstract
The [MeCOS]^−^ ion undergoes reaction with neutral thioacetic anhydride in an ion cyclotron resonance cell to yield an adduct [M+MeCOS]^−^ which decomposes principally by loss of CH~2~CS, thus establishing the occurrence of nucleophilic attack through O at the carbonyl centre.