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Ion attachment to van der Waals clusters: reactions of NO+ with Arm

✍ Scribed by M. Lezius; P. Scheier; T.D. Märk


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
414 KB
Volume
196
Category
Article
ISSN
0009-2614

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✦ Synopsis


A new method is described of rendering ionized neutral van der Waals clusters. This involves the association of NO + ions to a neutral argon cluster beam in a Nier-type ion source. This new (and alternative to electron and photon) ionization mode appears to be softer than electron impact ionization (i.e. leading to less fragmentation) and measured cluster ion distributions exhibit the typical icosahedral shell and subshell closures (i.e. in the range from n = 13 to n = 5 5 ) which are not present in the case of electron impact ionization.


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✍ T.D. Märk; P. Scheier; A. Stamatovic 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 459 KB

SO,-, S&-O-snd SO,?30-ifre proditced by &Won attachment to S@ ClWers under single coBision conditions. SOT, which is not produced at all in low-pressure ion sources, is more abundant than SCI&-and SO&30-. Measured relative attachment cross sections for these ions show significant diierences when co