Formation of SO−2, SO2·O− and SO2·SO− by electron attachment to van der waals SO2 clusters
✍ Scribed by T.D. Märk; P. Scheier; A. Stamatovic
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 459 KB
- Volume
- 136
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
SO,-, S&-O-snd SO,?30-ifre proditced by &Won attachment to S@ ClWers under single coBision conditions. SOT, which
is not produced at all in low-pressure ion sources, is more abundant than SCI&-and SO&30-. Measured relative attachment cross sections for these ions show significant diierences when compared to O-and SO-produced by attachment to S02, i.e. the first resonance is very eflficiently quenched in favor of SO,-production. This is in contrast to previous findings in 02, CO* and N30.
📜 SIMILAR VOLUMES
## Abstract Pulsed laser photolysis of O~3~ in a large excess of N~2~ has been used to generate O(^3^__P__) atoms in the presence of OCS. By observing chemiluminescence from the small fraction of electronically excited SO~2~ formed in the reaction of SO with O~3~, rate constants of (1.7 ± 0.2) × 10
The formation of SF + , SF 2 + , SO + and SO 2 + fragment ions from dissociative ionization of the SO 2 F 2 molecule has been studied by means of a trochoidal electron velocity selector coupled to a mass spectrometer. The ionization efficiency curves of ions were measured and their appearance energi