Ion association effects and phase separation in poly(propylene oxide) modified poly(dimethylsiloxane) complexed with triflate salts
✍ Scribed by P. Jacobsson; I. Albinsson; B.-E. Mellander; J.R. Stevens
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 547 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0032-3861
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📜 SIMILAR VOLUMES
Ah&r&-Ionic association in complexes of poly(propylene oxide) with alkali metal salts of thiocyanate, fluoroborate, and perchlorate anions was studied with Raman scattering and infrared transmission spectroscopy, Thiocyanate complexes are strongly coordinated through the nitrogen end of the anion. C
## Abstract **Summary:** The thermosensitive phase‐separation of poly(vinyl methyl ether) in water has been investigated by micro‐Raman spectroscopy in the presence of tetraalkylammonium bromides. The equilibrium distribution of both polymer and salts to the polymer‐rich and solvent‐rich phases was