Iodonium Zwitterions
β Scribed by Darryl D. DesMarteau; William T. Pennington; Vittorio Montanari; Brian H. Thomas
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 80 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
π SIMILAR VOLUMES
Whereas ion-pairing has been long recognized as playing a key role in organometallic chemistry, the zwitterionic feature of organotransition metal complexes has only recently become an influential factor in the design of cationic metal catalysts. The prospective situation of reversed polarity, with
A valence criterion previously developed by us is reinvestigated. The deviation from a standard valence is partitioned in HP and CI contributions to generate a more precise definition of diradicals and zwitterions. The method is compared with other criteria. It is used to classify a large number of