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Iodine and lithium intercalation into the high-Tc superconducting oxide Bi2Sr2CaCu2Oy

โœ Scribed by Masao Ohashi; Wendy Gloffke; M. Stanley Whittingham


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
319 KB
Volume
57
Category
Article
ISSN
0167-2738

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The effect of the iodine intercalation on the structure of high Tc superconducting oxide Bi2Sr2CaCu208 ha.~ been studied by high resolution electron microscopy. The iodine atoms intercalate in between the two Bi-O planes of the Bi202 layers, in a plane Pl perpendicular to the c axis of the unit cell

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Magnetic irreversibility data is presented for iodine intercalated Bi2Sr=CaCthO r single crystals. Iodine transfers charge both to the CuO2 planes and the BiO bilayers. The possibility of enhanced coupling along the c-axis through increased conductivity in the rocksalt block is not borne out in the