Two different kinds of stage-1 iodine intercalates of Bi 2 Sr 2 CaCu 2 O y with dissimilar T c have been prepared in order to understand the relationship between superconducting properties and electronic structures. According to the XRD analysis and the magnetic susceptibility measurements, it is fo
HREM study of the iodine intercalated superconducting oxide IBi2Sr2CaCu2Oy
β Scribed by B. Chenevier; S. Ikeda; K. Kadowaki
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 176 KB
- Volume
- 185-189
- Category
- Article
- ISSN
- 0921-4534
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β¦ Synopsis
The effect of the iodine intercalation on the structure of high Tc superconducting oxide Bi2Sr2CaCu208 ha.~ been studied by high resolution electron microscopy. The iodine atoms intercalate in between the two Bi-O planes of the Bi202 layers, in a plane Pl perpendicular to the c axis of the unit cell. A modulation is observed in this plane such that the major component of the iodine atoms displacement is parallel to the b axis. A model for the distribution of iodine and bismuth atoms in the average structure of IBi2Sr2CaCu2Oy, is presented.
π SIMILAR VOLUMES
Magnetic irreversibility data is presented for iodine intercalated Bi2Sr=CaCthO r single crystals. Iodine transfers charge both to the CuO2 planes and the BiO bilayers. The possibility of enhanced coupling along the c-axis through increased conductivity in the rocksalt block is not borne out in the