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Investigations on organo-tin compounds. VII the addition of organo-tin hydrides to olefinic double bonds

✍ Scribed by van der Kerk, G. J. M. ;Noltes, J. G. ;Luijten, J. G. A.

Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
853 KB
Volume
7
Category
Article
ISSN
0021-8871

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✦ Synopsis

Abstract

A new method for the synthesis of tin‐carbon bonds is described. The synthesis involves the non‐catalysed addition of organo‐tin hydrides to olefinic double bonds at moderate temperatures (60–100°). This method allows the preparation of a variety of hitherto unknown types of functionally substituted organo‐tin compounds, of which typical representatives are described.

The structure of the addition products is discussed briefly. It has been shown that the addition of organo‐tin hydrides to olefins does not follow the rule of Markownikow.

In a few cases a deviation from the expected addition reaction was observed. Examples of such anomalous reactions are given.

📜 SIMILAR VOLUMES

Investigations on organo-tin compounds.
Investigations on organo-tin compounds. VIII. preparation of some organo-tin hydrides
✍ van der Kerk, G. J. M. ;Noltes, J. G. ;Luijten, J. G. A. 📂 Article 📅 2007 🏛 Wiley (John Wiley & Sons) ⚖ 345 KB

## Abstract The preparation, according to the slightly modified procedure of Finholt __et al.__, of the following organo‐tin hydrides is described: triethyltin hydride, tri‐__n__‐propyltin hydride, tri‐__n__‐butyltin hydride, triphenyltin hydride, di‐__n__‐propyltin dihydride, di‐__n__‐butyltin dih

Investigations on organo-tin compounds.
Investigations on organo-tin compounds. IX. the preparation of some dialkyltin compounds with long-chain alkyl groups
✍ van der Kerk, G. J. M. ;Luijten, J. G. A. 📂 Article 📅 2007 🏛 Wiley (John Wiley & Sons) ⚖ 530 KB

## Abstract The preparation and properties are described of some di‐__n__‐hexyl‐, di‐__n__‐octyl‐, bis‐(2‐ethyl‐__n__‐hexyl)‐and bis‐(3 : 5 : 5‐trimethyl‐__n__‐hexyl)tin compounds, potentially interesting as non‐toxic stabilizers for vinyl plastics. An improved procedure is given for the determina