The study concerns a very sensitive electroanalytical method, based on derivative chronopotentiometry of the chromium (111) complex with 2-(5'-bromo-2'-pyridylazo)-5-diethyl aminophenol (5-Br-PADAP) accumulated adsorptively on the surface of a hanging mercury drop electrode. The detection limit is 6
Investigations on adsorption potentiometry: Part VI. Derivative adsorption chronopotentiometry of furazolidone
โ Scribed by Wenrui Jin; Yanhong Zheng; Xia Qu
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 332 KB
- Volume
- 262
- Category
- Article
- ISSN
- 0003-2670
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โฆ Synopsis
An electroanalyhcal method for the determmatlon of trace-amounts of furazobdone, based on derlvattve chronopotenttometry of furazohdone accumulated adsorptively on the surface of a hangmg mercury drop electrode, has been developed The dependences of the peak current of reduction of adsorbed furazohdone OR the preconcentratmn trme and the preconcentratlon potential are discussed The electrode reactlon was found to be totally lrreverslble Opttmum expenmental cnndltlons Include 9 0 x 10m3 mol I-' KOH and a prewncentratlon potential of -030 V (vs SCE) Under these condltlons, the detection lnmt and the lmear range are 1 OX lOA" and 3 4 x 10e9-1 4 x 10e6 md I-', respectively, for an accumulation time of 60 s The method was applied to samples of furazuhdone tablets
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A derivative chronopotentiometric method for the determination of ultratrace boron, based on adsorptive accumulation of a boron complex on the surface of a hanging mercury drop electrode, was developed. In order to form the boron(liD complex with 4-[(4-diethylamino-2-hydroxyphenyl)azo]-5-hydroxynaph
Equations of the derivative of time with respect to potential and of its peak potential and the peak half-width are derived for a reversible process in adsorption potentiometry in both stirred and unstirred solutions, when both oxidized and reduced forms #are strongly adsorbed and the Langmuir isoth