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Investigation of the unusual dependence of the rate of radical copolymerization on monomer ratio

✍ Scribed by S.M. Samoilov; L.S. Semenova; V.N. Monastyrskii


Book ID
118361170
Publisher
Elsevier Science
Year
1975
Weight
764 KB
Volume
17
Category
Article
ISSN
0032-3950

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Free-Radical Frontal Copolymerization: T
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## Abstract Frontal copolymerization is a process in which a spatially localized reaction zone propagates into a mixture of two monomers, converting them into a copolymer. In the simplest case of free‐radical copolymerization, a mixture of monomers and initiator is placed into a test tube. Reaction

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Styrene (M1) has been copolymerized with 0-, m-and p-halostyrenes (M2) at temperatures between 40 and ll0~C, using azoisobutyronitrile as initiator; the halostyrenes were labelled with 14C in the fl-position. The compositions of the copolymers were determined by liquid scintillation counting. ## Si

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The free-radical copolymerization of styrene with butyl acrylate was carried out in benzene and benzonitrile at 50Β°C. Differences between the apparent reactivity ratios determined in this work and those previously reported in bulk indicated noticeable solvent effects. This is explained by a qualitat