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Solvent effects on the free-radical copolymerization of styrene with butyl acrylate. I. Monomer reactivity ratios

✍ Scribed by Marta Fernández-García; Marina Fernández-Sanz; Enrique López Madruga; Rocio Cuervo-Rodriguez; Vicente Hernández-Gordo; M. C. Fernández-Monreal

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
162 KB
Volume
38
Category
Article
ISSN
0887-624X

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✦ Synopsis

The free-radical copolymerization of styrene with butyl acrylate was carried out in benzene and benzonitrile at 50°C. Differences between the apparent reactivity ratios determined in this work and those previously reported in bulk indicated noticeable solvent effects. This is explained by a qualitative bootstrap effect.

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