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Investigation of the SiH Bond Using an Ultraviolet Spectrophotometric Method

✍ Scribed by Jòzsef Nagy; Jòzsef Rèffy; Anna Borbèly-Kuszmann; Katalin Beckerpalossy

Book ID
108347376
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
458 KB
Volume
17
Category
Article
ISSN
0022-328X

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The rate constant for the reaction B~(~P)~P,+S~,H~ has been measured with the flash-photolysis resonance-fluorescence technique to be ( 1.35?0.12) x 10-'Oexp( -3.05 f0.3 kJ mol-'/RT) cm3 s-' over the temperature range 295-565 K. Theuncertainties represent ? lo in the Arrhenius parameters, while 95O/