## Abstract **Summary:** Polymer network formation in controlled/living radical crosslinking copolymerization of S/DVB initiated by a poly(S)‐TEMPO macroinitiator in aqueous miniemulsion at 125 °C is investigated. The crosslinking proceeded differently in miniemulsion (heterogeneous systems) and in
Investigation of the radical copolymerization of styrene and divinylbenzene
✍ Scribed by R. Okasha; G. Hild; P. Rempp
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 526 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0014-3057
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📜 SIMILAR VOLUMES
## Abstract Suspension copolymerization of styrene and divinylbenzene (DVB) was carried out using benzoyl peroxide as initiator and magnesium hydroxide as suspending agent in water at 80°C under nitrogen atmosphere to produce styrene–DVB copolymer beads. These beads were characterized by infrared s
## Abstract **Summary:** The nitroxide‐mediated controlled/living free radical copolymerization of styrene and divinylbenzene using a polystyrene‐TEMPO macroinitiator in aqueous miniemulsion and in bulk have been investigated. The crosslink densities were estimated based on the content of pendant v
## Abstract Network formation in the nitroxide‐mediated cross‐linking copolymerization of styrene and divinylbenzene (3 or 8.2 mol‐% relative to total monomer) using the nitroxide 2,2,6,6‐tetramethylpiperidinyl‐1‐oxy (TEMPO) at 125 °C can proceed markedly differently in aqueous miniemulsion compare