Suspension copolymerization of styrene and divinylbenzene: Formation of beads
β Scribed by D. C. Gupta; A. G. Beldar; R. Tank
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 114 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
Suspension copolymerization of styrene and divinylbenzene (DVB) was carried out using benzoyl peroxide as initiator and magnesium hydroxide as suspending agent in water at 80Β°C under nitrogen atmosphere to produce styreneβDVB copolymer beads. These beads were characterized by infrared spectroscopy, thermal gravimetric analysis, and scanning electron microscopy. Porosity generated in styreneβDVB copolymer beads by incorporation of solvents in the polymerization system was confirmed by SEM micrograph, apparent density, swelling measurements, and Brunauer, Emmett, Teller surface area. Β© 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3559β3563, 2006
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The crosslinking copolymerization of styrene-divinylbenzene (DVB) with 6% (w/w) DVB was investigated quantitatively by liquid chromatography (LC), viscosity, GPC, and static and dynamic laser light. Through these experiments, reaction order, mechanism, and evolution of molecular weight, size, polydi
The use of a mechanistic model-based experimental design technique to determine the polymerization conditions and polymer properties in suspension copolymerization of styrene and divinylbenzene is reported. The technique consists of using a mathematical model to design the polymerization conditions