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Investigation of the photoconversions of radicals in polyhydric alcohols,γ-irradiated at 77°K, by the method of electron paramagnetic resonance

✍ Scribed by I. E. Makarov; B. G. Ershov

Book ID
112420882
Publisher
Springer
Year
1970
Tongue
English
Weight
466 KB
Volume
19
Category
Article
ISSN
1573-9171

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Electron paramagnetic resonance studies
Electron paramagnetic resonance studies of spin trapping of the primary neutral radicals formed in γ-irradiated methanol
✍ S.W. Mao; Larry Kevan 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 295 KB

The primary neutral radicals in y-irradiated liquid methanol at 194°K have been spin trapped with phenyl-t-butyl nitrone. The principal primary radicals are CH20H and CH30. In contrast to earlier work, these radicals are formed with an initial ratio of CHzCH/CHaO J 1.5 which agrees with gas phase ma