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Investigation of the lowest triplet state of the pyrochlorophyllide a—apomyoglobin complex by zero-field optically detected magnetic resonance spectroscopy

✍ Scribed by Richard H. Clarke; Eugene B. Hanlon; Steven G. Boxer

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
308 KB
Volume
89
Category
Article
ISSN
0009-2614

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✦ Synopsis

The zero-lizld lluoresccnccdckctcd triplet state mpetlc reson3ncc spcctn hwc been obmincd for the pymchlorophyllidc a-apomyoglobm compln at 1 K The rnplct SICIIC zero-field sphltmgs Jnd spm sublevel dyn.mucs wcrc detcclcd on the rcsolwd features of the slrucrurcd lowtempcrzxture Iluoresccncc. Struclurrd ~luorcsccncc LS nol obscrvcd ior pyiuchlorophyhde a m XI atgzruc m3trLx under Idenricsl candlrions. Thrsc dara xc lnhxprcWd III wrms of Ihe loc.d bInding XI= of the pyrochlorophylhdc a chmmophorc ~II the pd& md the low-lcmper3lur2 conrornMon oi the protein lll3111\

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