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Investigation of the kinetics of epoxy resin hardening by a method which excludes their reaction with the material of the container

โœ Scribed by A. M. Noskov; V. N. Gogolev

Publisher
Springer US
Year
1974
Tongue
English
Weight
262 KB
Volume
20
Category
Article
ISSN
0021-9037

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A novel reaction for the functionalizati
A novel reaction for the functionalization of epoxy resins: New regio- and chemoselective ring-opening of epoxides with aryl silyl ether catalyzed by cesium fluoride
โœ Yoko Nambu; Takeshi Endo ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

By use of cesium fluoride as a catalyst, aryl or alkyl glycidyl ethers were ring-opened by aryl trimethylsilyl ether to produce O-protected aryloxyhydrins with a quantitative regioselectivity for the first time. Alkyl silyl ether was ineffective for this ring-opening. Hy the regioselective ring-ope