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Investigation of the formation of Strecker aldehydes from the reaction of Amadori rearrangement products with α-amino acids in low moisture model systems

✍ Scribed by D. R. Cremer; M. Vollenbroeker; Karl Eichner


Publisher
Springer
Year
2000
Tongue
English
Weight
85 KB
Volume
211
Category
Article
ISSN
0044-3026

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✍ George A. Olah; G. K. Surya Prakash; Yah Li Chao 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 153 KB

## Abstract Anchimerically assisted rearrangement, observed in the fluorination of some α‐amino acids with 70 : 30 (w/w) hydrogen fluoride/pyridine (by weight) in the presence of NaNO~2~, is substantially or fully suppressed by using the less acidic reagent 48 : 52 (w/w) hydrogen fluoride/pyridine.