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Investigation of the conformational properties of 4-deoxy-2,3-anhydro-α-DL-ribopyranoside by the IR spectroscopy method

✍ Scribed by L. K. Prikhodehenko; T. E. Kolosova; R. G. Zhbankov; A. Zamoiski; A. Banaszek


Book ID
110584123
Publisher
Springer US
Year
1994
Tongue
English
Weight
132 KB
Volume
61
Category
Article
ISSN
0021-9037

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Single crystals of benzyl3,4-anhydro-2-O-mesyl-6-O-trityl-a-~-altropyranoside (1) were tetragonal, space group P4,, with cell dimensions a = l&393(3), b = 16.393(2), c = 11.952(2) A, Z = 4. The 3,4\_anhydropyranose ring adopts a half-chair ('Ho) conformation. The conformations of 3,4-anhydro-a-Dhexo