Investigation of polycrystalline CdZnTe, CdMnTe, and CdTe films for photovoltaic applications
โ Scribed by A. Rohatgi; S.A. Ringel; R. Sudharsanan; P.V. Meyers; C.H. Liu; V. Ramanathan
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 651 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0379-6787
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โฆ Synopsis
Polycrystalline thin films of CdZnTe and CdMnTe have been grown by molecular beam epitaxy and metal-organic chemical vapor deposition, respectively, on CdS/SnO2/glass substrates, with bandgaps of 1.65-1.75 eV for the top of a two-cell tandem design. P-i-n cells were fabricated and tested using Ni/p+-ZnTe as a back contact to the ternary films. CdTe cells were also fabricated using both growth techniques, which resulted in 9 -10% efficiency and provided a baseline for ternary cell development. It was found that standard CdTe processing (400 ยฐC air annealing) reduces the ternary bandgaps from about 1.7 to about 1.55 eV, resulting in significantly reduced subgap transmission with cell efficiencies of 3 -4%. Optimum airannealing conditions were determined to retain the 1.7 eV bandgaps; however, the cell performance was still limited by both poor CdZnTe/CdS interface quality and high series resistance. The junction interface was found to improve by annealing in the presence of hydrogen, which resulted in Voc values from 0.500 V to as high as 0.65 V, but the cell performance became increasingly limited by series resistance. The effects of cell processing on the properties of the CdZnTe/CdS interface, the bulk CdZnTe film, and the back-contact region have been investigated to provide guidelines for achieving high efficiency in widegap ternary cells.
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