Investigation of Methacrylate Free-Radical Depropagation Kinetics by Pulsed-Laser Polymerization
β Scribed by Hutchinson, Robin A.; Paquet, Donald A.; Beuermann, Sabine; McMinn, John H.
- Book ID
- 126953928
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 108 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0888-5885
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π SIMILAR VOLUMES
An integral relationship, first given by Nishimura, has been applied to the bulk and solution polymerizations (dead-end data) of ethyl methacrylate. The kinetic rate constants calculated by this method for the bulk and solution cases are compared. The results are also compared with those previously
## Abstract Summary: The freeβradical polymerization kinetics of 4βacetoxystyrene (4βAcOS) is studied over a wide temperature range. Pulsedβlaser polymerization, in combination with dual detector sizeβexclusion chromatography, is used to measure __k__~p~, the propagation rate coefficient, between 2