## Abstract In this study, a new phase transfer catalyst has been synthesized and characterized, which is used for the study of kinetics and mechanism of the free radical polymerization of ethyl methacrylate. The reactions were carried out using peroxodisulfate as initiator in inert and unstirred c
Free radical polymerization of ethyl methacrylate: A kinetic investigation
✍ Scribed by Huceste H. Çatalgil; Bahattin M. Baysal
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 176 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
An integral relationship, first given by Nishimura, has been applied to the bulk and solution polymerizations (dead-end data) of ethyl methacrylate. The kinetic rate constants calculated by this method for the bulk and solution cases are compared. The results are also compared with those previously obtained for solution polymerization by the dead-end method.
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## Abstract From a phenomenological point of view, the Mayo‐Lewis terminal model can describe both copolymer composition and the variation of copolymerization rate for the ethyl α‐benzoyloxymethylacrylate/methyl methacrylate/benzene/2,2′‐azoisobutyronitrile system.