Investigation of butadiene polymerization in the presence of the catalyst system π-crotyl nickel chloride-ethyl aluminium dichloride-ethyl boron fluoride

Kinetic laws of ethylene polymerization

Kinetic laws of ethylene polymerization in the presence of homogeneous catalysts including titanocene and Al(C2H5)2Cl in ethyl chloride medium and mathematical description of the process—I. Ethylene polymerization in the presence of the catalytic system Al(C2H5)2Cl-“Blue complex”

✍ A.V. Agasaryan; G.P. Belov; S.P. Davtyan; M.L. Eritsyan 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 408 KB

Effect of ethylene concentration, catalyst component and their molar ratio on the polymerization stationary rate, the yield and molecular weight of the polyethylene formed have been investigated. A kinetic scheme for the ethylene polymerization is proposed: a mathematical description of the process