Investigation of an unusual rearrangement
โ Scribed by David B. Smith; Todd R. Elworthy; David J. Morgans Jr.; Janis T. Nelson; John W. Patterson; Alfredo Vasquez; Ann Marie Waltos
- Book ID
- 103401980
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 175 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The lactone 2 was found to be a co-product of the BF etherate induced cyclization of epoxyisogermacrone 2. The ketal 3 when treated with 100% HCOOH afforded the lactone 5-while underthe same condltlons the ketol 4 gave the corresponding ester 5. A mechanism is suggested for the rearrangements. Rece
## 3-Chloro henzisothiazole-1, l-dioxide ("pseudoeaccharinchloride") I reacts very smoothly with syn-aldoximes and ketoximes to form "pseudosaccharin oxime ethers" II ').