Upon treatment with (PhIO) n or PhI(OAc) 2 , 1,5-diaza-cis-decalin undergoes oxidation at the more hindered position along with fragmentation to yield the ring-expanded bislactam. The cis and trans 1,5-diazadecalins both undergo the same elimination indicating a potential stereoelectronic preference
โฆ LIBER โฆ
An unusual oxidative rearrangement of [7]-helicene
โ Scribed by Matthew J. Fuchter; Marko Weimar; Xuezheng Yang; Dilraj K. Judge; Andrew J.P. White
- Book ID
- 113930431
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- French
- Weight
- 406 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0040-4039
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