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Investigating Direct Alkynylation at the Bridgehead of Bicyclic Cages Using Silver(I) Acetylides

✍ Scribed by Rebecca H. Pouwer; Jason B. Harper; Kamesh Vyakaranam; Josef Michl; Craig M. Williams; Carsten H. Jessen; Paul V. Bernhardt


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
186 KB
Volume
2007
Category
Article
ISSN
1434-193X

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✦ Synopsis


Abstract

Silver(I) acetylides facilitate direct carbon–carbon bond formation at the bridgehead position of adamantane, and in some instances related systems such as carborate anions and bicyclo[2.2.2]octanes. Substrate constraints along with attempts to further understand the underlying mechanism are presented. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)


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