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Cover Picture: Investigating Direct Alkynylation at the Bridgehead of Bicyclic Cages Using Silver(I) Acetylides (Eur. J. Org. Chem. 2/2007)

✍ Scribed by Rebecca H. Pouwer; Jason B. Harper; Kamesh Vyakaranam; Josef Michl; Craig M. Williams; Carsten H. Jessen; Paul V. Bernhardt

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 111 KB
Volume: 2007
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200790002

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Investigating Direct Alkynylation at the

Investigating Direct Alkynylation at the Bridgehead of Bicyclic Cages Using Silver(I) Acetylides

✍ Rebecca H. Pouwer; Jason B. Harper; Kamesh Vyakaranam; Josef Michl; Craig M. Wil 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 186 KB

## Abstract Silver(I) acetylides facilitate direct carbon–carbon bond formation at the bridgehead position of adamantane, and in some instances related systems such as carborate anions and bicyclo[2.2.2]octanes. Substrate constraints along with attempts to further understand the underlying mechanis