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Investigating Cation Binding in the Polyoxometalate-Super-Crown [P8W48O184]40−

✍ Scribed by Thomas Boyd; Dr. Scott G. Mitchell; David Gabb; Dr. De-Liang Long; Prof. Leroy Cronin

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
641 KB
Volume
17
Category
Article
ISSN
0947-6539

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The complex host-guest chemistry… …of the crown-type cluster [P 8 W 48 O 184 ] 40À has been studied by a combination of 31 P NMR spectroscopy and isothermal titration calorimetry. This cluster which was originally reported in 1985 is witnessing a recent surge in interest. Herein its selectivity for

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## Abstract The immobilization of polyoxometalates (POMs) into thin organized films is of major importance for the development of functional devices like electrochromic films and catalysts. We investigate herein two methods to incorporate the wheel‐shaped tungstophosphate [H~7~P~8~W~48~O~184~]^33–^